You can download the user account data from the system to a CSV file by following these steps:
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Go to Site Administration > Users > Accounts > Bulk user actions
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Click the "Add all" button
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Under "With selected users..." select "Download"
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Click the "Go" button
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On the following page click the "Download" button
This will output all regular user fields and custom profile fields but if the profile field is translated (from a menu choice) it will display the menu number instead of the value.